화학공학소재연구정보센터
Fuel, Vol.87, No.6, 905-914, 2008
Modeling the temperature in coal char particle during fluidized bed combustion
The temperatures of a coal char particle in hot bubbling fluidized bed (FB) were analyzed by a model of combustion. The unsteady model includes phenomena of heat and mass transfer through a porous char particle, as well as heterogeneous reaction at the interior char surface and homogeneous reaction in the pores. The parametric analysis of the model has shown that above 550 degrees C combustion occurs under the regime limited by diffusion. The experimental results of temperature measurements by thermocouple in the particle center during FB combustion at temperatures in the range 590-710 degrees C were compared with the model predictions. Two coals of different rank were used: lignite and brown coal, with particle size in the range 5-10 mm. The comparisons have shown that the model can adequately predict the histories of temperatures in char particles during combustion in FB. In the first order, the model predicts the influence of the particle size, coal rank (via porosity), and oxygen concentration in its surroundings. (C) 2007 Elsevier Ltd. All rights reserved.