Co-combustion of pulverised coal with a woody biomass, cedar chip was conducted in a lab-scale drop-tube furnace (DTF) to investigate the synergetic interaction between the inorganic elements of different fuels and the emissions of sub-micron particles (particles smaller than 1.0 mu m in size, PM(1)) and super-micron particles (particles in the size range of 1.0-10 mu m, PM(1+)) during co-firing. The mass fraction of cedar chip in fuel blend ranged from 10% to 50%. All the fuels were burnt in air at two furnace temperatures, 1200 and 1450 degrees C. The results indicate that, under an identical calorific input, combustion of cedar chip alone favored the emission of sub-micron PM(1), which is dominated by volatile elements including K, Ca, Fe, Na and P. A large fraction of K and Na were most probably present as gaseous vapors in the furnace. The other metals mainly condensed into nano-scale nuclei which subsequently coagulated into a variety of sizes in flue gas. Coal combustion alone favored the release of super-micron particles rich in Al and Si. Emission of PM upon co-firing was a function of both cedar chip share and furnace temperature. At a small mass fraction for cedar chip in fuel blend, e. g. 10% tested here, interaction between the inorganic elements of single fuels was insignificant at either furnace temperature. Accordingly, the quantities of PM(1) and PM(1+) emitted from co-firing at 10% cedar chip were slightly higher than from the combustion of coal alone, due to the contribution of cedar chip. Significant interaction between the inorganic elements of single fuels was observed for co-firing of coal with >10% cedar chip at the furnace temperature of 1450 degrees C. As has been confirmed, adding 20-30% cedar chip to coal resulted in the shift of approximately 90% of PM(1) and 50% PM(1+) into coarse ash particles. For the cedar chip-derived alkali vapors and nano-scale/sub-micron particles, the rates of their shift into larger particles were influenced by two competing routes, homogeneous coagulation and surface reaction with coal-derived kaolin. In contrast, the shift of super-micron particles was primarily determined by their collision probability with the coal-derived mineral grains in bulk gas. A sticky surface for particles is also essential. The shift of individual metals into coarse ash differed distinctly from one another. Crown Copyright (C) 2010 Published by Elsevier Ltd. All rights reserved.