This article presents a detailed experimental characterization of the reburning process in a large-scale laboratory furnace. Natural gas, pine sawdust and pulverized coal were used as reburn fuels. Initially, the study involved the collection of in-flame combustion data, without reburning, in order to define appropriate locations for the injection of the reburn fuels. Next, flue-gas data were obtained for a wide range of experimental conditions using the three reburn fuels and, subsequently, detailed measurements of local mean O(2), CO, CO(2), HC and NO(x) concentrations, and gas temperatures have been obtained in the reburn zone for three representative furnace operating conditions, one for each reburn fuel studied. The flue-gas data revealed that the sawdust reburning leads to NO(x) reductions comparable or even higher than those attained with natural gas reburning, while coal reburning yields much lower NO(x) reductions. The detailed data obtained in the reburn zone indicates that the reburning process remains active throughout all the reburn zone in the cases of natural gas and sawdust reburning, while in the case of coal reburning its relatively low volatile matter content is insufficient to establish an effective reburn zone. In the cases of the sawdust and coal reburning the burnout levels remain approximately constant, regardless of the NO(x) emissions reduction, with the sawdust reburning leading to higher particle burnout performance than the coal reburning. (C) 2010 Elsevier Ltd. All rights reserved.