| 학회 |
한국고분자학회 |
| 학술대회 |
2004년 봄 (04/09 ~ 04/10, 고려대학교) |
| 권호 |
29권 1호, p.94 |
| 발표분야 |
고분자 합성 |
| 제목 |
The Polymerization of Olefins By Using New Type Phenoxy-Imine Nickel(ll) Catalyst |
| 초록 |
A number of highly active olefin polymerization catalysts based on both early and late transition metals have been discovered. Notable examples are nickel complexes with a diimine ligand or a phenoxy-imine ligand. These transition metal complexes exhibit activities comparable of those of the group 4 metallocene catalysts. Recently, we have synthesized well-defined phenoxy-imine Nickel (ll) catalysts bearing various substituents on the aryl ring on the basis of a ligand-oriented catalyst design concept in which ligands play the predominant role for activity and polymerized olefins by theses complexes. Here, we report on the preparation and characteirzation of phenoxy-imine nickel (ll) catalysts and its detailed catalytic performance for the polymerization of olefins. |
| 저자 |
곽창훈1, 하창식2, 김일3
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| 소속 |
1부산대, 2초미세화학공정시스템연구센터, 3고분자공학과 |
| 키워드 |
Olefin Polymerization; Phenoxy-Imine ligand
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| E-Mail |
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