화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO))
권호 23권 1호
발표분야 고분자_포스터
제목 Development of High Performance Organic Field-Effect Transistors with Bio-Derived Solvent-Processable Random Terpolymers
초록 Donor-acceptor (D-A) conjugated polymers based on diketopyrrolopyrrole (DPP) have been utilized as backbones for high-performance organic field-effect transistors (OFETs). Our group previously reported two ε-branched side chain substituted D-A polymers, PDPP-selenophene (Se) and PDPP-(E)-2-(2-(thiophen-2-yl)vinyl)thiophene (TVT), which exhibited different phys-ical properties. In this work, bio-derived solution-processable OFETs were realized using the set of diketopyrrolopyrrole (DPP)-based random copolymers, by controlling irregularity of polymer backbone. The remarkable ambipolar charge mobilities were obtained from 2-methyltetrafuran-processed OFETs compared to chlorobenzene-processed ones. This study will provide guidelines for developing highly efficient green plastic transistors.
저자 이해랑1, 강소희2, 정아영3, 양창덕2, 오준학1
소속 1서울대, 2울산과학기술원, 3포항공과대
키워드 Organic field-effect transistor; Polymer semiconductors; Random terpolymers; Eco-friendly solution-processing
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