화학공학소재연구정보센터
학회 한국재료학회
학술대회 2021년 가을 (11/24 ~ 11/26, 경주 라한호텔)
권호 27권 2호
발표분야 C. 에너지 재료 분과
제목 The Formation Mechanism for Printed Silver-Contacts of Silicon Solar Cells using the Current Injection
초록 The electrodes of Si solar cells are formed via screen printing using metal paste for mass production. Firing, a high-temperature (< 800℃) annealing process, is conducted for sintering metal particles and etching the passivation layer. In our previous report, we proposed a method for reducing this contact resistance from 5 mΩ∙cm2 to 1 mΩ∙cm2 by applying a current during the firing of a phosphorous-doped n+ emitter in an p-type Si wafer without a SiNx passivation layer. According to the results, applying a current during the firing process of Si solar cells is expected to reduce the required firing temperature. In the present study, a current (3A) was applied between the screen-printed electrode and phosphorus-doped n+ emitter in a p-type Si wafer with a SiNx passivation layer during a low-temperature firing process from 350 ℃ to 600 ℃. Given that the major effects of the proposed methods are the reduced contact resistance with the promoting the SiNx etching reaction. Cross-sectional scanning electron microscopy images at different firing temperatures demonstrated that current injection during firing promoted the etching of the SiNx layer. Ultimately, a solar cell efficiency of 19.0% similar to that of a reference sample fired at a higher temperature was obtained using the proposed method.
저자 최동진1, 박현정1, 심명섭1, 배수현2, 김동환1, 이해석3, 강윤묵3
소속 1고려대, 2한국과학기술(연), 3KU-KIST 에너지환경대
키워드 Silicon solar cells; Metallization; Current injection; Low-temperature; Screen-printed Ag contact
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