| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Synthesis of Novel Molecular Explosive-embedded Binder System using 1,2,3-Triazole "Click Reaction” |
| 초록 |
We performed synthesis project for making prepolymer which has high-energetic molecular explosive group with polyol type of low molecular weight. Triazole embedded polyetherdiol were synthesized by copper(I)-catalyzed 1,3-dipolar cycloaddition that called “Click Chemistry”. This click reaction has very mild reaction conditions and insensitive to water and oxygen. The triazoles have high heat of formation (1H-1,2,3,-triazole : 273KJ/mol) and triazole-based salts are used as energetic materials. It was carried out using cupper(II) sulfate pentahydrate (Cu(II)SO45H2O) / sodium ascrobate system as catalyst. The poly(GAP-co-THF) were converted easily with alkyne in high yield ＞98% in the presence of TEA base and polar aprotic solvent to give the high viscous new 1,2,3-triazole-embedded energetic polyetherdiol without any noticed change of difunctionality. |
| 저자 |
정권영1, 이범재1, 고선덕1, 김태중1, 지상철1, 박종혁1, 김진석2
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| 소속 |
1충남대, 2국방과학(연) |
| 키워드 |
1; 3-dipolar cycloaddition; click chemistry; 1; 2; 3-Triazolyl polyetherdiol
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| E-Mail |
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