| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
| 권호 |
32권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Novel Titanatrane Complexes Containing Electronically and Sterically Modified Imino-2,2’,2’’-triethanolate Ligand |
| 초록 |
The use of triethanolamine ligand in the chemistry of atrane in which five-membered chelating rings are present has broadened its application across the periodic table. Generally, most studies in the formation of atrane have focused on the main group elements such as silicon, phosphorus, aluminum and tin. In the case of titanatranes, only few examples of atrane with modified triethanolateamine ligands were reported in literature Examples of titanatranes containing triethanolamine-based ligand with controlled steric hindrance have, to our knowledge, not been reported. Synthesis and characterization of new tetradentate ligands and their titanium complexes with controlled steric hindrance will be demonstrated. The X-ray structures of titanium complexes and their application for polymerization catalysis will be also shown. |
| 저자 |
문상덕1, 김소한1, 홍연진1, 고영호1, 이준승2, 도영규2, 김영조1
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| 소속 |
1충북대, 2한국과학기술원 화학과 |
| 키워드 |
titanatrane; modified triethanolamine ligand
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| E-Mail |
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