| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터) |
| 권호 |
39권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis and OPV application of Low Bandgap Conjugated Polymers based on 3,6-dithiophen-2-yl-diketopyrrolopyrrole |
| 초록 |
A novel conjugated polymer comprising diketopyrrolopyrrole (DPP) was successfully synthesized via direct heteroarylation polymerization in a moderate condition. DPP was used as an electron-defect unit which was coupled with various electron-rich comonomeric units to build efficient small bandgap donor polymers for organic photovoltaic applications. Electron-rich comonomeric units were also incorporated to improve increase the solubility of DPP-based material. The 3-alkylthiophene was copolymerized with DPP via direct heteroarylation polymerization in a moderate condition and had a relative high yield. The chemical structure and optical properties were precisely characterized by NMR, GPC, cyclic voltammetry and spectrophotometer. A series of bulk-heterojunction optical solar cells of ITO/PEDOT/polymer:PC61BM/LiF/Al were prepared and the photovoltaic performance of each solar cell was carefully measured. The surface topology of each layer of solar cells was also investigated. |
| 저자 |
김상용, 권순재, 곽경, 윤태기, 안태홍, 권용구
|
| 소속 |
인하대 |
| 키워드 |
opv; diketopyrrolopyrrole
|
| E-Mail |
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