화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 봄 (04/29 ~ 05/01, BEXCO (부산))
권호 19권 1호
발표분야 고분자_포스터
제목 Organic-inorganic hybrid perovskite Solar Cells based on New Polymeric Hole Transporting Materials with High Hole Mobility
초록 In this work, perovskite solar cells based on a (CH3NH3PbI3) and a Poly[2,5-bis(2-decyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione-(E)-1,2-di(2,2’-bithiophen-5-yl)ethene] (PDPPDBTE) hole transport polymer was prepared. The optical and electrical properties of perovskite nanocrystals used as a light harvester yielded a 9.2% power conversion efficiency that exceeded the value (7.6%) obtained from spiro-MeOTAD. The hydrophobicity of the polymer prevented water permeation into the porous perovskite heterojunction. As the result, the long-term stability of the PDPPDBTE devices, as measured over 1000 hours under a humid atmosphere, guarantees the practical applicability of these solid-state hybrid solar cells under outdoor working condition.
저자 김태완, 강경호, 권영수, 임종철, 박태호
소속 POSTECH
키워드 perovskite solar cell; hole transport layer; long term stability
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