| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO)) |
| 권호 |
40권 2호 |
| 발표분야 |
의료용 고분자 부문위원회 II |
| 제목 |
Preparation and Characterization of Polyester diblock copolymer with functional group for in situ forming hydrogel |
| 초록 |
MPEG-b-PCL as a candidate thermo-responsive polymer that featured favorable properties. However, MPEG-b-PCL has not functional group with side chain, and thereby limited to application. To solved this problem, we introduced functional group in PCL backbone to enhance facilitate a variety of applications. We synthesized of MPEG-b-PCL based-block copolymers with functional pendant groups on the PfCL block by ring-opening polymerization. The thermal properties of the block copolymers depend on the functional pendant group on PfCL composition. The derivatized MPEG-b-(PCL-co-PfCL) di-block copolymer solutions exhibited sol-to-gel phase transitions upon a temperature increase. The sol-to-gel phase transition depended on both the type of functional group on the PfCL and the PfCL content in the PCL segment. These results indicate that MPEG-b-(PCL-co-PfCL) di-block copolymer solutions could be used as thermo-responsive in situ gel-forming systems. |
| 저자 |
김문석, 김재호, 박지훈, 권진선, 권두연, 이보근
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| 소속 |
아주대 |
| 키워드 |
Hydrogel; Polyester; Functional group; Thermo-responsive
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| E-Mail |
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