| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
분자전자 소재 및 소자 기술(분자전자 부문위원회) |
| 제목 |
IMPACT OF POSITION OF ELECTRON WITHDRAWING CYANO (CN) GROUPS ON PHOTOPHYSICAL PROPERTIES IN SUBSTITUTED PHENYLENEVINYLENES |
| 초록 |
In this report, we discuss the photophysical properties of two symmetrically substituted phenylene-vinylene D-A-D′-A-D type siblings. The positional impact of these cyano groups on the singlet one-photon absorption transition behavior was characterized through their absorption and fluorescence spectra in solution. Two-photon absorption cross-section was measured in two-photon induced fluorescence method. A theoretical ab initio and semiemperical quantum calculation was employed for investigation of their linear and nonlinear photophysical properties. |
| 저자 |
김란희1, 이광섭1, 박진순1, Karin Schmidt2, Jean-Luc Brédas2
|
| 소속 |
1한남대, 2Georgia Institute of Technology / School of Chemistry and Biochemistry |
| 키워드 |
Two-photon absorption; Cyano group; position on the vinylene; intramolecular distortion
|
| E-Mail |
|
