화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2013년 봄 (04/24 ~ 04/26, 광주 김대중컨벤션센터)
권호 19권 1호, p.1000
발표분야 환경
제목 Thermochemical Kinetic Aspects of Solidification and Reduction of CO2
초록 A new concept of carbon cycle can be suggested in which the carbon regeneration is done  with low quality energy after the carbon is oxidized producing high quality energy. If we can get high quality energy by putting in low quality energy, CO2 emission can be minimized with the development of technology gathering waste energies to be utilized in the suggested cycle or ultimately speaking, carbon can be recycled perpetually if the cycle produces no additional CO2.  Stabilization of solid CO2 can be explained that the energy barrier is generated when it took the linear form. Once the free molecule is fixed its Gibb's free energy increases partly due to the entropy decrease and partly due to the enthalpy increase. In this way, the conversion of CO2 to carbon is made more favorable and carbon regeneration can be done with lower quality (i.e., lower temperature) energy. Starting from this concept, further development can bring down the reaction temperature lower and lower, and the range of the useful energy will become broader and broader.  
저자 김장규
소속 POSTECH
키워드 carbon dioxide; solidification; reduction; polymer
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