| 학회 | 한국공업화학회 |
| 학술대회 | 2013년 봄 (05/01 ~ 05/03, ICC JEJU) |
| 권호 | 17권 1호 |
| 발표분야 | 포스터-에너지저장변환 |
| 제목 | Excitation Energy Transfer for Increasing Photocurrent in Aqueous-Based Photovoltaic Devices |
| 초록 | We present that conjugated oligoelectrolytes (COEs) are useful photosensitizers to increase photocurrent generation in aqueous-based photovoltaic devices, an artificial photosynthetic device. In a hydrophobic medium, COEs have a high quantum yield over 90% because they do not interact with polar molecules via radiationless energy transfer. Thus, when COEs are co-assembled with an acceptor dyes whose absorption spectrum is well overlapped with the emission spectrum of COEs, an efficient energy transfer occurs via the Forster resonance scheme. A photoanode modified with COEs and Nile red in a vertical assembly shows enhanced photocurrent generation due to excitation energy transfer. Acknowledgments. This work was funded by the National Research Foundation (2012-0007432 and 2012-047716), the Ministry for Health and Welfare, Korea (A10301712131330200), and the Ministry of Knowledge Economy (K00060054-55505) |
| 저자 | 박주현, 김정태, 문경환, 양진호, 윤정주, 조현진, 최재혁 |
| 소속 | 중앙대 |
| 키워드 | Fluorescence resonance energy transfer; Photovoltaic Devices; Nile red; Conjugated oligoelectrolyte |
