| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO)) |
| 권호 |
23권 1호 |
| 발표분야 |
환경·에너지_포스터 |
| 제목 |
The effect of milling and postmilling recrystallization on SAPO-34 for methanol to olefins conversion |
| 초록 |
Methanol to olefin (MTO) reaction is an alternative route for producing light olefins from abundant resources of natural gas, coal, and biomass, instead of limited oil resources. Especially, silicoaluminophosphate (SAPO)-34 has excellent catalytic performance in the MTO reaction with highly selectivity for light olefins, due to cylinder-like cages with small 8-ring pore openings restricting the release of large hydrocarbons. However, the micropores of SAPO-34 suffers from the diffusion limitation causing a fast coke deposition and thus catalytic deactivation. In an attempt to improve the catalytic lifetime, we focused on the effect of milling and postmilling recrystallization on the morphological, physical and acidic properties of the SAPO-34. Ultimately, their modification was investigated in the aspect of improving the rapid deactivation toward the MTO reaction. |
| 저자 |
이수언, 이유진, 김주완, 김정랑, 정광은, 정순용
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| 소속 |
한국화학(연) |
| 키워드 |
SAPO-34; methanol; olefin; MTO; recrystallization; milling
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| E-Mail |
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