화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2008년 봄 (05/09 ~ 05/10, 한양대학교(안산))
권호 12권 1호
발표분야 우수논문(구두)
제목 Ni(0)/NHC Catalyzed Cross-Coupling of Pentaerithritol Tetrakis(benzenesulfonate) with Alkyl Grignard Reagent
초록 The nickel-catalyzed cross-coupling reactions of pentaerythritol tetrakis(benzenesulfonates) with alkyl Grignard reagents produced unsymmetrical biphenyl and terphenyl derivatives, which are of great interest due to their biological and optical properties, in the presence of Ni/N-heterocyclic carbene (NHC) catalysts. Ni/NHC catalyst could allow the coupling reaction to undergo at room temperature, which would make this reaction useful for the parallel/combinatorial chemistry.
저자 김철배, 박광용
소속 중앙대
키워드 nickel-catalyzed; N-heterocyclic carbene; NHC; alkyl Grignard reagents
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