| 학회 |
한국고분자학회 |
| 학술대회 |
2003년 가을 (10/10 ~ 10/11, 부경대학교) |
| 권호 |
28권 2호, p.160 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Synthesis, Characterization, Stimuli-Sensitive and Metal Binding Properties of Novel Betaine-Type Polyampholytes |
| 초록 |
Polyampholytes as a simple model for proteins and nucleic acids constantly attract the attention of researchers due to the presence of both acidic and basic groups in the macromolecular chains. A series of novel hydrophobically and hydrophilically modified monomers from acetoacetic ester and various alkylamines were synthesized. Novel water-soluble and water-swelling betaine-type polyampholytes were obtained via Michael addition reaction followed by radical copolymerization with various сomonomers. The kinetics and mechanisms of the copolymerization of the betaine-type monomers was evaluated. The linear polyampholytes were be characterized by potentiometric titration, viscosimetry, FTIR, NMR, SEM, TGA, DSC, and GPC. The stimuli-sensitive properties of the amphoteric gels was studied in dependence of pH, ionic strength, water-organic solvent mixtures and as a function of the DC electric field. The ability of the polymers to form complexes with metal ions was also studied. |
| 저자 |
노정균, 성영주, 김종범, Sarkyt E. Kudaibergenov, Kurt E. Geckeler
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| 소속 |
광주과학기술원 신소재공학과 |
| 키워드 |
Polyampholytes; Hydrogel; Stimuli-Sensitive Properties; Metal Binding Properties
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| E-Mail |
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