화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU))
권호 20권 2호
발표분야 에너지저장변환_포스터
제목 Organic-inorganic hybrid composite membrane for Vanadium Redox Flow Battery Applications
초록 Sulfonated poly (phenylene oxide) – nano sized silica (SiO2) hybrid composite membrane was prepared for enhance the unit cell performance of vanadium redox flow battery application. Compared to other hydrocarbon polymers, the low cost of PPO were sulfonated through the chlorosulfonic acid (CSA). The inorganic SiO2 nano particles were dispersed in the polymer matrix through the facile chemical synthetic techniques. Fourier transform infrared spectroscopy FTIR, x-ray diffraction (XRD) and transmission electron microscopy (TEM) analysis were characterized for functional group and structural analysis. The physico-chemical characterization of degree of sulfonation (DS), water uptake, swelling ratio, ion exchange capacity (IEC) and ionic conductivity (IC) were measured to the sPPO and hybrid membranes. Compared to various concentration of organic-inorganic materials, the composition of sPPO/1% SiO2 membrane shows the excellent performances in the physico-chemical characterizations.
저자 SADHASIVAM THANGARASU, 정호영, 임민화, 문건오, 박미정, 노현준
소속 Chonnam National Univ.
키워드 Sulfonated poly (phenylene oxide); nano sized SiO2; high ionic conductivity; VRFB applications
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