| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터) |
| 권호 |
36권 2호 |
| 발표분야 |
고분자합성-구조제어중합 |
| 제목 |
Iron (III)-Mediated Acrylonitrile polymerization via Generation of Activators by Monomer Addition (GAMA) ATRP |
| 초록 |
The small amount of Iron (III)-catalyzed AN (Acrylonitrile) polymerization via generation of activators by monomer addition (GAMA) for atom transfer radical polymerization (ATRP) was successfully employed using DPMPP (diphenyl-(2-methoxy phenyl) phosphine) as ligands in the absence of any additives .The living feature of the obtained polymer was further verified by a chain extension of PAN with St using obtained PAN as a macroinitiator via GAMA ATRP. Well-controlled polymerizations were carried out without any reducing agents or thermal initiators, yielding PAN with high molecular weight (＞150000) and relatively low polydispersity(＜1.3) |
| 저자 |
진상웅1, Mohd Yusuf Khan2, 류원석2, 노석균1
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| 소속 |
1영남대, 2Yeungnam Univ. |
| 키워드 |
AN; GAMA ATRP; IRON
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| E-Mail |
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