화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2012년 가을 (10/31 ~ 11/02, 대전컨벤션센터)
권호 16권 2호
발표분야 포스터-에너지저장.변환
제목 Influence of oxygen functional groups on ammonia adsorption of NiO-templated nanoporous carbons
초록 The scope of this work was to control the surface functional groups of nanoporous carbons (NPs) by oxidizing agents treatments and to investigate the relation between oxygen functional groups and ammonia removal efficiency. The NPs were directly prepared from a cation exchange resin by the carbonization of a mixture with Ni acetate. N2/77 K adsorption, Boehm’s titrations, and X-ray photoelectron spectroscopy (XPS) analyses were employed to confirm the physicochemical properties of NPs. The ammonia removal efficiency was confirmed by temperature programmed desorption (TPD) technique. It was also found that the oxidation treatment led to an increase in ammonia removal efficiency of NPs, mainly due to an increase of acid oxygen functional groups (such as carboxyl) on NPs surfaces.
저자 이슬이, 맹룡월, 박수진
소속 인하대
키워드 Nanoporous carbons; Ammonia adsorption; Carboxyl group; NiO-template; Acid treatment
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