화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2012년 봄 (05/09 ~ 05/11, 김대중컨벤션센터)
권호 16권 1호
발표분야 석유화학.윤활유
제목 The Effect of Reaction Conditions on Aqueous Phase Reforming of Ethylene Glycol over Platinum supported Mesoporous Carbon Catalyst
초록 Ordered mesoporous carbons CMK-9, which has a 3-dimensional framework and hollow type pore structure, and its supported platinum catalysts were prepared. The effect of reaction conditions (reaction temperature, pressure, and weight hourly space velocity (WHSV)) on the aqueous phase reforming of ethylene glycol has been studied. The conversion of carbon to gas and hydrogen yield increased in proportion to the reaction temperature and corresponding system pressure, whereas low WHSV was favorable for hydrogen yield and conversion of carbon to gas without decreasing the selectivity of hydrogen and alkane. The reaction scheme describing formation of the main gas and liquid products via various pathways was also proposed and discussed.
저자 김호동1, 박현주2, 김태완2, 정광은2, 채호정2, 정순용2, 김철웅2, 정영민3, 이창하1
소속 1연세대, 2한국화학(연), 3SK이노베이션
키워드 촉매; 수상개질반응; 수소. 메조포러스카본
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