화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 무기재료_포스터
제목 High catalytic performance of Raspberry-Like Gold Nanoparticles (Au RLNPs) and enhancement of stability by silica coating
초록   Raspberry-like gold nanoparticles (Au RLNPs) synthesized through the reduction of HAuCl4 using non-ionic surfactant (Brij35) and NaOH show high catalytic performance in the reduction of 4-nitrophenol and ethanol electrooxidation due to their high-surface roughness. However, Au RLNPs are easily changed to spherical or aggregated nanoparticles by treatment with acids, thiols, and cationic surfactants (e.g., CTAB), making it difficult to sustain the catalytic activity. To improve their stability and reusability, Au RLNPs were successfully encompassed within silica shell (Au RLNP@SiO2 NPs). Furthermore, the prepared Au RLNP@SiO2 NPs could be further encapsulated with titanium dioxide (Au RLNP@SiO2@TiO2), resulting in a catalyst with photocatalytic performance.
저자 유효종, 최순, MAIDUYHIEN, 문영서
소속 한림대
키워드 Gold nanoparticles; Silica coating; photocatalysis; core-shell structured catalyst
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