화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 고분자합성-구조제어중합
제목 Analysis of the properties by content of end-group for polycarbonate(PC) in melt polymerization process
초록 There are two processes to polymerize polycarbonate in the petrochemical industry: One is interfacial polymerization and the other is melt polymerization(melt PC). Recently, the latter is mostly used in that it is eco-friendly process. The most difference of product produced by two systems is the content of specific end-group. It detects a little bit value in interfacial polymerization, while it generally has more content in melt polymerization. It is supposed that the more content of the end-group is, the bigger change of the property induce as surrounding environment. In order to analyze an effect of the end-group, polycarbonate substituted to other end-group was made from melt PC using a suitable end-capping agent. And then, several properties were examined like melt index and color. As the result, the end-capped PC showed less change of the properties than general melt PC. It was verified that the properties of melt PC is adversely affected by the specific end-group.
저자 이수란, 임병훈, 박관휘, 장병옥
소속 호남석유화학
키워드 polycarbonate; melt polymerization; end-capping; end-group
E-Mail