| 초록 |
Polyhedral oligomeric silsesquioxane (POSS) is an intermediate (R-Si-O2/3)n between silica and silicone. POSS has a great thermal property and high chemical resistance because of its rigid silica-like core structure. In this study, POSS-with azide group was synthesized and reacted with a triple bond-containing diaminotriazine to make triazine monomer containing POSS through click-chemistry. Hybrid triazine polymer containing POSS was prepared by the condensation polymerization of triazine monomer containing POSS with 3,3’-Dithiodipropionic acid. Hybrid triazine polymer with POSS was characterized H1-NMR, FT-IR, TGA, DSC, and SEM. |
