화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2013년 봄 (05/01 ~ 05/03, ICC JEJU)
권호 17권 1호
발표분야 포스터-촉매
제목 Transesterification of rapeseed oil to biodiesel by modified heteropolyacid catalyst
초록 Biodiesel, a promising non-toxic, biodegradable, ecologically friendly alternative fuel, is produced by transesterification of triglycerides in oils and fats with alcohols, catalyst. In conventional process for biodiesel production, homogeneous base catalysts show high yield of FAME (fatty acid methyl ester) derived from oil. But these catalysts are corrosive to reactor and make saponification reaction which interrupts transesterification. Especially, homogeneous catalytic reaction requires a separation, and purification steps, which contribute additional cost for producing biodiesel. Heterogeneous catalyst, easy to separation from product, less toxic and recyclable, is widely studied in biodiesel production. In this work, we prepared heterogeneous catalyst incorporated heteropolyacid with basic aromatic heterocycle. Influences of reaction temperature, MeOH/Oil ratio, reaction time, incorporation ratio were also studied.
저자 이기천, 전유권, 박명근, 박세준, 설용건
소속 연세대
키워드 biodiesel; transesterification; heterogeneous catalyst
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