| 학회 |
한국화학공학회 |
| 학술대회 |
2009년 가을 (10/22 ~ 10/23, 일산 KINTEX) |
| 권호 |
15권 2호, p.2337 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Studies on Fischer-Tropsch synthesis over cobalt based supported catalysts |
| 초록 |
Recently, gas to liquid (GTL) process has been received much attentions because of high oil prices and global warning. Cobalt based catalysts are receiving widespread attention as the preferred Fischer-Tropsch synthesis (FTS) catalysts for GTL process. The cobalt-based catalysts supported on Al2O3 and modified Al2O3 were prepared by impregnation method and characterized by N2-adsorption, XRD, SEM, TEM, and TPR techniques. The broadening of XRD peak revealed nanosized Co3O4 crystallites less than 7nm. TEM data showed the nanosized particles (＜5nm) of Co3O4 crystallites. The performance of these catalysts for FTS were tested in a fixed bed reactor under the conditions 240oC, 2.5MPa, H2/CO feed molar ratio of 2.0 for 40h. The dependence of crysrallite size and reducibility of Co3O4 on the supports were investigated with FTS activity, CO conversion and product distribution in a fixed bed reactor system. |
| 저자 |
박문주1, 김소정1, 강정식1, 이상득1, 송광호2, 문동주1
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| 소속 |
1한국과학기술(연), 2고려대 |
| 키워드 |
fischer-tropsch; catalyst; cobalt; gas to liquid
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| E-Mail |
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| 원문파일 |
초록 보기 |
