화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2005년 봄 (04/22 ~ 04/23, 여수대학교)
권호 11권 1호, p.634
발표분야 에너지/환경
제목 소성 Dolomite 수화물계 화학열펌프의 고체 반응층 전열해석
초록 This study was carried out to investigate the heat-storage/-release characteristics of the thermochemical reaction of the calcined Dolomite and steam system for the application of chemical heat pump with the packed bed shape experimental apparatus.
Our results from the studies are as follows ;
MgO of the calcined dolomite can be regard as an inert material. Because the reaction was proceeded from the packed bed input to packed bed output and from wall to center, it could be thought that the rate determining step is not the reaction itself but the heat transfer. It was found that all of calcined Dolomite packed bed kept the reaction temperature of about 750K throughout the entire part of the bed, immediately after the steam was introduced exothermic reaction of hydration was proceeded from the packed bed input to packed bed output and from wall side to center. Two dimensional (radial and circumferential) partial differential equations, concerning heat and mass transfer rate in the packed bed of calcined Dolomite, are solved numerically to describe the characteristics of the reaction in the cylindrical reactor. The solution reads rate of reaction in the packed bed reactor depends on the temperature and concentration of reactants.
저자 이한규1, 김종식1, 박영해2, 이영세3, 홍민혁3
소속 1계명대, 2영남이공대, 3상주대
키워드 Calcined Dolomite; chemical heat pump; heat-storage
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