화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터)
권호 40권 1호
발표분야 고분자구조 및 물성
제목 Enhanced anti-chemical oxidation property of hydrocarbon polymer with Ce/crown-ether complex on pendant position for PEMFC application
초록 The effect of cerium ions (Ce3+) on the anti-oxidation and other properties of sulfonated poly(ether ether ketone) (sPEEK) membrane was studied, as it quenches the hydroxyl radicals, the major oxidation promoter in fuel cell operation. Cerium (Ce) was introduced along with 15-crown-5-ether to form a coordination complex to prevent both the migration of Ce3+ ions from the membranes and the direct interaction with sulfonic acid groups in sPEEK. The chemical and physical structures of the composite membranes were investigated using FT-IR, 1H NMR, SEM, EDX, and SAXS.
저자 박중화, 김덕준
소속 성균관대
키워드 membrane; PEMFC; oxidation; stability; cerium
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