화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 기능성 고분자
제목 Production of edge-thionic acid-functionalized graphene nanoplatelets retaining graphitic layered structures for lithium ion batteries as anode materials.
초록 Herein, we could introduce carbon disulfide (CS2) at the edges of graphene nanoplatelets (GnPs) with rich -C=S/-C-S bonds via ball-milling graphite in the presence of CS2. The resultant edge-thionic acid-functionalized GnPs (TAGnPs) exhibited a larger accessible surface area and smaller particle size than pristine graphite. Importantly, the TAGnPs retained a long-range-ordered graphitic layered structure similar to pristine graphite. When the TAGnPs are used as anode materials for LIBs, they displayed superior rate capability compared to pristine graphite and the reference edge-hydrogenated GnPs (HGnPs), which mainly have -C-H bonds at their edges.
저자 노혁준1, Qinghua Fan2, 정선민1, 전인엽3, Jiantie Xu2, 백종범1
소속 1UNIST, 2South China Univ. of Technology, 3원광대
키워드 graphite; Edge functionalization; Thionic acid; Lithium ion batteries
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