학회 | 한국화학공학회 |
학술대회 | 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터) |
권호 | 22권 2호, p.2361 |
발표분야 | 촉매 및 반응공학 |
제목 | Ordered mesoporous FeMOx (M = Al or Zr) catalysts for high temperature Fischer-Tropsch synthesis |
초록 | Chemical conversion process of syngas to value-added clean fuels and chemical intermediates through high temperature Fischer-Tropsch synthesis (FTS) reaction was investigated using ordered mesoporous Fe2O3 with Al2O3 or ZrO2 incorporation in the main frameworks. The improved structural stability with an irreducible metal oxides such as Al2O3 and ZrO2 were mainly attributed to the strongly interacted Fe2O3 with irreducible metal oxides by forming mixed-metal oxides. The Al and Zr-incorporated Fe2O3 catalysts was synthesized by varying a molar ratio of Fe/Al or Fe/Zr using nano-casting replica method. In order to characterize the structural properties of the catalysts, powder X-ray diffraction (XRD), temperature-programmed reduction (H2-TPR), Brunauer-Emmett-Teller (BET) analysis, and transmission electron microscopy (TEM) analyses were mainly performed. Keywords: Fischer-Tropsch Synthesis(FTS); Mesoporous Fe2O3; irreducible ZrO2 and Al2O3; structural stability. |
저자 | 조재민, 배종욱 |
소속 | 성균관대 |
키워드 | 비균질촉매 |
VOD | VOD 보기 |
원문파일 | 초록 보기 |