| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center)) |
| 권호 |
21권 1호 |
| 발표분야 |
나노 |
| 제목 |
Fabrication of anisotropic modified silica nanotube for nanocarrier |
| 초록 |
Anisotropic silica nanotubes with different internal and external functional groups can be utilized as a smart nanocarrier for catalyst. Silica nanotube with ca. 200 nm-diameter were fabricated by vapor phase synthesis using AAO as a hard template. The internal and outer surface of the silica nanotubes were asymmetrically functionalized by selective polymer and silane treatment. After introducing Pd salt inside the silica nanotube, Pd was reduced via bubbling of hydrogen gas. The silica nanotubes containing Pd nanoparticles were used as nanocarriers for the Heck reaction catalysis of olefination and have a high efficiency up to 99% and TON(turnover number) of 7.5 which was calculated based on GC/MS and TGA. |
| 저자 |
서영덕, 장정식
|
| 소속 |
서울대 |
| 키워드 |
silica nanotube; nanocarrier
|
| E-Mail |
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