학회 |
한국화학공학회 |
학술대회 |
2010년 가을 (10/21 ~ 10/22, 대전컨벤션센터) |
권호 |
16권 2호, p.2436 |
발표분야 |
고순도 정밀화학 제품 생산을 위한 크로마토그라피와 모사이동층 (SMB) 분리 기술 심포지엄 |
제목 |
Zeolite-Organic Hybrid Material and Its Application |
초록 |
Great attentions to develop new route for preparing the organic-inorganichybrid zeolites have been paid because of overcoming the limitation of theiruses in catalysis and separation from the lack of delicate functionality.Zeolite-Organic Hybrid Material can be used for the heterogeneous catalysts,separation of biomolecules and the manufacturing of enantiopure chemicalsand pharmaceuticals, as well as heterogeneous enantioselective catalysts.We will introduce the methods how to prepare amino acid exchanged zeoliteand, ammonium with long alkyl chain exchanged zeolite and its applicationfor chiral separation and catalysts.We introduce some size- andshape-controlled inert zealots instead of silica as the base material ofstationary phase, and both archival and chiral selectors to the basematerial for both separations. Separation tests with BTEX mixture showedgood performance enough for using as the stationary phase of large-scale SMBfor petroleum industry.Some subsequent MD simulations showed goodcorrelation between the retention times and binding free energy.Some otherapplication will be introduced also. |
저자 |
김정섭1, 박희상1, 장상훈1, 김광연2, 이창하3, 장석규4, 서 곤5, 노경태1
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소속 |
1(주)카이로라이트, 2(사)분자설계(연), 3연세대 화공생명공학과, 4중앙대 화학과, 5전남대 응용과학공학부 |
키워드 |
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E-Mail |
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원문파일 |
초록 보기 |