| 초록 |
In this study, a series of aliphatic polyamide hybrids with porphyrin was synthesized. Porphyrin is a good electron donor and is put into a polymer system as a conductive filler for a conductive polymer composite. Aliphatic polyamides were synthesized from hexamethylene diamine (HMDA), tris(2-aminoethyl)amine (TAEA) and various dicarboxylic acid. These dicarboxylic acid have long alkyl chain as long as from 9 to 12, which are derived from biomass. Porphyrin was combined with not reacted amine of TAEA moiety. Structural characterization of hybrid materials was confirmed by UV-Vis absorption, FL, FT-IR, DSC, and so on. |
