| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO)) |
| 권호 |
40권 2호 |
| 발표분야 |
분자전자 부문위원회 II |
| 제목 |
A Pseudo-Regular Alternating Conjugated Copolymer Using an Asymmetric Monomer: A High-Mobility Organic Transistor in Nonchlorinated Solvents |
| 초록 |
We have described the first example of a conjugated pseudo-regular alternating copolymer PDPP–TVS that is soluble in nonchlorinated solvents. The conjugated backbone of this polymer is strictly irregular due of the irregular distribution of T and S moieties in the TVS units along the chain; however, the sp2-hybridized carbon backbone structure displayed the same periodicity as in the regularly alternating copolymers PDPP– TVT and PDPP–SVS. The synthesized polymers were highly soluble in nonchlorinated solvents, and they also showed molecular orientations and packing structures similar to those observed in PDPP–TVT and PDPP–SVS. OFET devices fabricated using these novel polymers in non-chlorinated solvents exhibited a high µ up to 8.2 cm 2 V −1 s −1 . |
| 저자 |
김윤희1, 조길원2, 강보석2, 송은주2, 최현호2, 백장열1
|
| 소속 |
1경상대, 2포항공대 |
| 키워드 |
organic transistors; nonchlorinated solvent; high mobility; irregularity; asymmetric monomer
|
| E-Mail |
|
