| 학회 |
한국공업화학회 |
| 학술대회 |
2011년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터) |
| 권호 |
15권 1호 |
| 발표분야 |
환경.에너지 |
| 제목 |
Selective Bicarbonate Formation in CO2 Absorption Process Based Secondary Cyclic Amines |
| 초록 |
We demonstrate that secondary cyclic amine(PiP; piperidine and PiZ; piperazine) derivatives with substituents at 2- or 5-position afforded carbamate ions as main adduct in the CO2 absorption process. From the results of 13C-NMR, the piperidines with methyl or hydorxylmethyl substitutent at2 position(PiP-Me, PiP-MeOH) and 2,5-dimethylpiperazine(DM-PiZ) represented that the bicarbonate ions were selectively generated with carbamate ions as minor. The initial absorption rates of amines for CO2 capturing were shown a tendency of PiP＞PiP-Me＞DM-PiZ＞MEA＞PiP-MeOH. |
| 저자 |
신만섭1, 이윤만1, 박윤국1, 남성찬2, 황광진1
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| 소속 |
1홍익대, 2한국에너지기술(연) |
| 키워드 |
carbamate; bicarbonate; CO2; absorption
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| E-Mail |
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