| 학회 | 한국화학공학회 |
| 학술대회 | 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터) |
| 권호 | 22권 2호, p.2499 |
| 발표분야 | 촉매 및 반응공학 |
| 제목 | Zinc Acetate-based Catalysts for the Cycloaddition Reaction between CO2 and Epoxides |
| 초록 | The synthesis and characterization of zinc(II) complexes such as [Py(Pz)2]Zn(OC(=O)Me)2 (1) and [Py(Me2Pz)2]Zn(OC(=O)Me)2 (2), where ligands Py(Pz)2 and Py(Me2Pz)2 are tridentate 2,6-bis(pyrazol-1-yl)pyridine and 2,6-bis(3,5-dimethylpyrazol-1-yl)pyridine, respectively, will be shown. The single crystal X-ray diffraction analysis demonstrated that compound 2 was monomeric with six-coordinated zinc center. We will present their application of new zinc compounds 1 and 2 as effective catalysts for the cycloaddition between CO2 and epoxides in the presence of various kinds of cocatalysts such as n-Bu4PBr, n-Bu4NI, n-Bu4NBr, n-Bu4NCl, PPNCl, and DMAP. Acknowledgment: 본 연구는 지역혁신창의인력양성사업(2014H1C1A1066874)의 지원을 받아 수행되었음 |
| 저자 | 신민석, 오범진, 김영조 |
| 소속 | 충북대 |
| 키워드 | 유기금속촉매 |
| 원문파일 | 초록 보기 |
