| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터) |
| 권호 |
36권 2호 |
| 발표분야 |
고분자 구조 및 분석－Scattering & Spectroscopy |
| 제목 |
Unexpected MOFs, [(MTCPP)(NHMe2)2](DMF)4 (M = Co and Cu), synthesized from DMF solvolysis |
| 초록 |
The metal-organic framework [(MTCPP)(NHMe2)2](DMF)4 (M = Co and Cu) was prepared by hydrothermal synthesis. It is characterized by X-ray diffraction. Due to DMF solvolysis, the product contained dimethylamine ligands which are unexpected. This is the first reported case that unexpected porphyrin-based MOF is prepared due to DMF solvolysis. In the structure of [(MTCPP)(NHMe2)2](DMF)4, unusual strong hydrogen bonding network is adopted which is formed by dimethylamine ligands from DMF solvolysis. In the hydrogen bonding network, strong hydrogen bond between H atom in OH group and O atom in another molecule, strong hydrogen bond between H atom in NH group and O atom in another molecule and weak hydrogen bond between H atom in CH group and O atom in another molecule are contributing to the stable structure of the product. |
| 저자 |
신용무, 조철희, 최은영
|
| 소속 |
KAIST부설 한국과학영재학교 |
| 키워드 |
metal organic framework; DMF; solvolysis
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| E-Mail |
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