| 학회 |
한국화학공학회 |
| 학술대회 |
2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스)) |
| 권호 |
10권 2호, p.2336 |
| 발표분야 |
촉매/반응공학 |
| 제목 |
Catalytic activity and immobilization of new enantioselective chiral Co (III) salen complexes in the hydrolytic kinetic resolution of epichlorohydrine |
| 초록 |
The syntheses of optically pure chemicals have gained significant potential over recent years. Chiral catalysts get more important nowadays. Especially the heterogeneous chiral catalysts offer practical advantages of the facile separation from reactants and products. Several immobilization strategies have been shown to give stable and active heterogeneous catalysts. So, we synthesize chiral Co(III) salen complexes bearing on BCl3. And this Co(III) Salen complexes are immobilized on the functionalized silica gel. This catalysts are very reactive and enantioselective in the hydrolytic kinetic resolution of racemic ECH(epichlorohydrine) with water. |
| 저자 |
신창교, 김건중
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| 소속 |
인하대 |
| 키워드 |
Chiral catalysts; hydrolytic kinetic resolution
|
| E-Mail |
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| 원문파일 |
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