| 학회 |
한국화학공학회 |
| 학술대회 |
2005년 가을 (10/21 ~ 10/22, 인하대학교) |
| 권호 |
11권 2호, p.2677 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Asymmetric Kinetic Resolution of Racemic Epoxides in Bimodal Meso/Macroscopic Pore Structure |
| 초록 |
Aroute to synthesize porous materials with a bimodal macro/ mesoscopic pore system has been investigated in this work. Polystyrene with sub-micrometer size was used as a template in the synthesis. The resulting mesoporous silica wall replicated inversely the morphology of polystyrene template and had highly ordered three-dimensional arrays of macro pores. Large and moldable meso/macro porous silica monoliths could be obtained in centimeter scale by using monodispersed polystyrene beads and PEO-PPO-PEO/SBA-15 sol solutions. These bimodal structured porous silicates have been used as supports for asymmetric kinetic resolution of racemic epoxides to synthesize optically pure epoxide. |
| 저자 |
신창교, 김수현, 김건중
|
| 소속 |
인하대 |
| 키워드 |
macropore; monolith; mesoporous silica; sol-gel; SBA-15; enantioselectivity; epoxide
|
| E-Mail |
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| 원문파일 |
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