| 학회 |
한국공업화학회 |
| 학술대회 |
2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스)) |
| 권호 |
10권 2호 |
| 발표분야 |
촉매 |
| 제목 |
Asymmetric Hydrolytic Kinetic Resolution of Terminal Epoxides Catalyzed by Immobilized Polymeric Chiral Salen Complexes on SBA-15 having 3-dimensional Type Pore System |
| 초록 |
SBA-15 having very large 3-dimensional pore system was synthesized by the method reported in the paper by treatment of dimethylcarbonate after impregnation of KCl as a catalyst for partial removal of SiO2 as tetramethoxysilane. The chiral salen catalyst immobilized on SBA-15 showed higher conversion than that anchored on SBA-15 in asymmetric HKR reaction of terminal epoxides with water under the same conditions. |
| 저자 |
이영희, 신창교, 안철흥, 김건중
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| 소속 |
인하대 |
| 키워드 |
Polymeric chiral salen; SBA-15; Asymmetric ring opening
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| E-Mail |
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