화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 대학원생 구두발표
제목 Ultrahigh density array of CdSe nanorods using block copolymer template for CdSe/P3HT hybrid solar cells
초록 We fabricated CdSe/poly(3-hexylthiophene) (P3HT) hybrid solar cells with ultrahigh density array (4 x 1011 in-2) of the CdSe nanorods having a length of ~ 100 nm, a diameter of ~ 20 nm, and an inter-distance of neighboring nanorods of ~ 20 nm. The vertically oriented CdSe nanorods on indium tin oxide-coated glass were prepared by electrodeposition into nanoporous template made of polystyrene-block-poly(methyl methacrylate) copolymer (PS-b-PMMA) thin film. The short-circuit current of this device was three-times greater than that of another solar cell prepared by CdSe/P3HT bilayer film, indicating that more efficient charge separation at the interface and facilitated charge transport were achieved through the vertically oriented CdSe nanorods. The power conversion efficiency of the solar cell cased on CdSe nanorod array/P3HT hybrid was twice greater than that of another based on CdSe/P3HT bilayer films.
저자 권승철, 심명선, 이정인, 이태우, 조길원, 김진곤
소속 포항공과대
키워드 block copolymer; template; CdSe; hybrid solar cells; nanostructure
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