| 학회 |
한국공업화학회 |
| 학술대회 |
2011년 가을 (11/02 ~ 11/04, 경원대학교) |
| 권호 |
15권 2호 |
| 발표분야 |
고분자 |
| 제목 |
Synthesis of microporous polyurea networks by cross-linking copolymerization of tetrakis(4-aminophenyl)methane, tetrakis(4-aminophenyl)silane and 2,2’,7,7’-tetraamino-9,9’-spirobifluorene with diisocyanate |
| 초록 |
Microporous polyurea networks were synthesized by cross-linking copolymerization of tetrakis(4-aminophenyl)methane, tetrakis(4-aminophenyl)silane and 2,2’,7,7’-tetraamino-9,9’-spirobifluorene with 1,6-diisocyanatohexane. We were able to obtain colloidal dispersions (sols) at concentrations below critical gelation point. The microporous characteristics of the networks were studied with varying the comonomer compositions. The nanopaticles obtained from the organic sol state were characterized using dynamic light scattering, atomic force microscope, and scanning electron microscope. This work was supported by a Korea Science and Engineering Foundation (KOSEF) grant. [2010-0026421] |
| 저자 |
안민균, 박지웅
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| 소속 |
광주과학기술원 |
| 키워드 |
Polyurea network; Organic sol-gel; copolymerization
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| E-Mail |
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