화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 기능성 고분자
제목 Polymerization of epoxy resins initiated by benzylsulfonium salts
초록 An epoxy-imidazole resin system was used to form an anisotropic conducting film (ACF) for electronic equipment applications. Cationic cure of epoxy resins is very rapid and has shown potential in significant industrial processes which require fast reaction rates. In this study, benzyltetrahydrothiophenium hexafluoroantimonate, 1-(p-methoxybenzyl)tetrahydrothiophenium hexafluoroantimonate, benzylphenyl methyl sulfonium hexafluoroantimonate, and benzyl p-hydroxyphenyl methyl sulfonium hexafluoroantimonate were synthesized, and were used as latent thermal initiators for epoxy resins. The curing behavior of these sulfonium salts to epoxy resin was examined using DSC. The curing times were estimated at 150 ℃ and 180 ℃ using an indentation method. The reaction rate of these sulfonium salts were compared with other curing agents such as imidazole derivatives.
저자 김선희, 이동호, 양민희, 신재섭
소속 충북대
키워드 epoxy resin; latent curing agent; benzylsulfonium salt
E-Mail