화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO))
권호 40권 2호
발표분야 기능성 고분자
제목 Sulfonated poly(arylene ether ketone) based membranes with low vanadium ion permeability for all vanadium redox flow battery applications
초록 In this study, proton exchange membranes are prepared from poly(arylene ether ketone) having long pendant sulfoalkyl groups as proton conductor for the membrane of all vanadium redox flow battery system. Sulfonated PAEK with flexible side chain were prepared by polycondensation of 4,4-Difluorobenzophenone with 2,2-Bis(3-amino-4-hydroxyphenyl)hexafluoropropane and Bisphenol-AF, followed by post-sulfonation using 1,3-butanesultone. We confirmed the structure by using H1-NMR, FT-IR. And the properties of membrane such as ion conductivity, ion exchange capacity were tested for all vanadium redox flow battery applications.
저자 김덕준, 양선희
소속 성균관대
키워드 proton exchange membrane; hydrocarbon polymer; low vanadium ion permeability; vanadium redox flow battery
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