| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
| 권호 |
46권 2호 |
| 발표분야 |
분자전자 부문위원회 Ⅰ,Ⅱ |
| 제목 |
Stretchable High-performance N-type Regio-Isomeric Polymers Based on Asymmetric Electron-Accepting Repeat Unit |
| 초록 |
We have incorporated a newly formulated electron-accepting monomer unit(EA) into a series of n-type low-bandgap polymers with combination of cyclopentadithiophene (CDT) and indacenodithiophene (IDT) co-monomers. Controlling the regiregularity of the asymmetric electron-accepting monomer moiety has provided regio-isomeric polymer structures such as semi-regioregular (s-PCDT-EA and s-PIDT-EA) and regiorandom (r-PCDT-EA and r-PIDT-EA), respectively. We systematically performed comparative studies with respect to both the regio-chemistry control and CDT vs IDT repeat units in the polymers. All the polymers show excellent n-channel field-effect transistors with high electron mobility. Not only electron mobility, high intrinsical stretchability and organic phototransistor properties are also observed. The utilization of electron-accepting monomer can greatly facilitate the molecular design of next-generation n-type semiconducting polymers for stretchable and conformable electron devices. |
| 저자 |
김현욱1, 박하영1, 박종민1, 조용준2, 정성훈2, 오준학1, 양창덕2
|
| 소속 |
1서울대, 2울산과학기술원 |
| 키워드 |
Organic semiconducting polymer; Organic field effect transistor; Intrinsically stretchable device; Phototransistor; Electron accepting monomer
|
| E-Mail |
|
