| 학회 |
한국화학공학회 |
| 학술대회 |
2008년 가을 (10/23 ~ 10/24, 부산 BEXCO) |
| 권호 |
14권 2호, p.2603 |
| 발표분야 |
분리기술 |
| 제목 |
Absorption of CO2 into GMA solution containing MCM-41 catalyst |
| 초록 |
Ionic liquid (IL) of MCM-41 (CP-MS41) via the immobilization of triethylamines (TEA-CP-MS41) was used as a catalyst of the reaction between carbon dioxide and glycidyl methacrylate (GMA). Absorption rate of carbon dioxide into GMA solutions containing IL, which was measured in a semi-batch stirred tank with a plane gas-liquid interface at 101.3 kPa, was used to obtain the reaction kinetics from analysis of the mass transfer mechanism accompanied by the elementary reactions based on the film theory. An empirical correlation formula between the reaction rate constants and the solubility parameters of the solvents, such as toluene, N-methyl-2-pirrolidinone, and dimethyl sulfoxide, was presented. |
| 저자 |
박상욱1, 손영식1, 황병진1, 오광중1, 김성수2
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| 소속 |
1부산대, 2부산가톨릭대 |
| 키워드 |
absorption; carbon dioxide; glycidyl methacrylate; MCM-41
|
| E-Mail |
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| 원문파일 |
초록 보기 |
