| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Dye-Sensitized Solar Cells with Ionic Liquid-Based Pseudo-solid Ionic Gel Electrolytes |
| 초록 |
Although an impressive light-to-electricity conversion efficiency, solvent-based electrolytes have practical limitation of sealing and long-term operation. So we designed pseudo-solid ionic gel electrolytes by introducing two different block copolymers based on 1-propyl-3-methyl imidazolium iodide/Iodine ionic liquid electrolytes. The gelation of block copolymer formed gel electrolyte systems having different modulus might have effect on interfacial contact. Also, we added 1-methylbenzimidazole into optimized I-/I3- redox couple which is expected to provides not the co-adsorbent’s effect in electrolyte but also the improved electron transfer capacity of the I-/I3- redox couple. J-V curves of DSSCs with 0.16 cm2 active area were tested at the equivalent of one sun at AM 1.5 illumination under the mask of 0.25cm2. Through the analysis of J-V characteristics and Electrochemical Impedance Microscopy, we observed that ionic gel electrolytes offer specific benefits over the ionic liquids. |
| 저자 |
강덕기1, 원종옥1, 유순동1, 이용건2, 강용수3
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| 소속 |
1세종대, 2서울대, 3한양대 |
| 키워드 |
Dye-Sensitized Solar Cells; Ionic Liquid; Ionic Gel
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| E-Mail |
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