화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터)
권호 34권 1호
발표분야 기능성 고분자
제목 Synthesis and Photovoltaic properties of Low band gapPolymers based on 2-pyran-4-ylidemalononitrile derivatives, 10-hexylphenothiazine and 9,9-dihexylfluorene.
초록 Organic photovoltaic systems exhibiting low cost and high efficiency in solar energy conversion are strategically important and actively pursued worldwide. In order to improve their efficiency, the design of new materials that absorb at longer wavelengths (or good electron mobility) is of substantial interest. We synthesize a series of new copolymers based on 2-pyran-4-ylidenemalononitrile derivatives and 10-hexyl-phenothiazine or 9,9-dihexylfluorene to get low band gap and high Voc. A series of copolymers were synthesized successfully through the Suzuki coupling reaction. In this report, the optical, electrochemical, and photovoltaic properties of the blend of new copolymers and PCBM will be discussed.
저자 유혜리, 신웅, 정미선, 박상준, 박정배, 김주현
소속 부경대
키워드 solar cell; OPVCs; donor; band gap
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