화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 고분자합성
제목 Synthesis of Low Bandgap Diketopyrrolopyrrole-Based Copolymers for Photovoltaic Applications
초록 Novel low bandgap polymers (PDPPTT) of electron-withdrawing diketopyrrolo[3,4-c]pyrrole(DPP) and electron-donating thieno[3,4-b]thiophene (TT) with different alkyl chains were synthesized using various cross-coupling techniques. The conjugated backbone composed of TT and DPP comonomer units effectively reduced the energy bandgap of the final polymers. The length of the alkyl units of the TT comonomer was changed to both enhanced the solubility of the conjugated polymer and modulated the energy level of the polymers. Using these polymers, we prepared a bulk heterojunction (BHJ) solar cell devices of ITO/PEDOT:PSS/ DPPTT:PCBM/LiF/Al and measured its photovoltaic performance by using various characterization techniques.
저자 권순재, 안태홍, 곽경, 윤지연, 김상용, 권용구
소속 인하대
키워드 synthesis; DPP
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