화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션)
권호 20권 1호
발표분야 고분자_포스터
제목 Synthesis of Norbornene ester polymers using (ŋ3-substituted allyl) palladium (NHC) complexes as catalyst and their structure-property relationships.
초록 Synthesis of norbornene ester polymers using (ŋ3-substituted allyl) palladium (NHC) complexes as catalyst and the relationship between chemical structures and properties of obtained poly(norbornene esters) were investigated. Norborenen ester monomers were synthesized from the esterification of 5-norbornene-2-methyl alcohol and aromatic carboxylic acids. Polymerization catalyst, (ŋ3-substitued allyl) palldium(NHC) complex, was synthesized according to the literature procedure. 1H-NMR spectroscopy was carried out for determining chemical structure of monomers and polymers. The molecular weight of the polmers were measured by GPC and the thermal properties were analyzed by TGA and DMA.
저자 이두현, 선우예림, 김영준
소속 성균관대
키워드 Polynorbornene; esterification; thermal propertiy; palladium complex
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